Step 1: Understanding the Concept
A copolymer is made from two or more different monomers. A homopolymer is made from a single monomer.
Step 2: Homopolymers
Orlon comes from acrylonitrile, PVC from vinyl chloride and Teflon from tetrafluoroethylene. Each uses a single monomer.
Step 3: The copolymer
PHBV is made from 3-hydroxybutanoic acid and 3-hydroxypentanoic acid, so it is a copolymer (and is biodegradable).
Final Answer:
PHBV is the copolymer.
\[ \boxed{\text{(C) }\text{PHBV}} \]