Concept:
Fireclay refractories are alumino-silicate refractories. They contain both silica and alumina.
Step 1: Fireclay refractories are made from fireclay, which mainly contains:
\[
Al_2O_3 \quad \text{and} \quad SiO_2
\]
Step 2: Alumina provides refractoriness and improves high-temperature performance.
Step 3: Silica is also present in significant amount.
Step 4: The alumina content in fireclay refractories generally lies in the range:
\[
25-45\%
\]
Therefore, the correct answer is:
\[
\boxed{25-45\%}
\]