Concept:
Adsorption is generally an exothermic process and decreases randomness of particles.
Step 1: Effect on enthalpy.
During adsorption, attractive forces are formed between adsorbent and adsorbate. Hence heat is released:
\[
\Delta H < 0
\]
So enthalpy decreases.
Step 2: Effect on entropy.
Gas or solute particles become fixed on the surface, so randomness decreases:
\[
\Delta S < 0
\]
Step 3: Final answer.
Thus, adsorption is accompanied by decrease in enthalpy and decrease in entropy.