Concept:
According to the proton (H$^+$) transport theory, stomatal opening involves active ion transport and metabolic changes in guard cells.
Step 1: Understand daytime process.
During daytime:
• Starch in guard cells is converted into phosphoenolpyruvate (PEP)
• PEP is converted into malic acid
Step 2: Formation of protons.
Malic acid dissociates as:
\[
\text{Malic acid} \rightarrow \text{Malate}^{-} + H^{+}
\]
Thus, protons ($H^+$ ions) are released in guard cells.
Step 3: Analyze options.
• (A) Cellulose formation → Not related $\times$
• (B) Sugar to starch → Night process $\times$
• (C) Starch to malic acid → Proton formation \checkmark
• (D) Potassium malate at night → Incorrect $\times$
Step 4: Conclusion.
\[
\text{Protons are formed when malic acid dissociates in guard cells}
\]