Step 1: Understanding the vector product.
The vector product of two vectors \( \vec{A} \) and \( \vec{B} \) is zero when the vectors are parallel. That is, \( \vec{F}_1 \) and \( \vec{F}_2 \) must be parallel.
Step 2: Analyzing the given vectors.
The vector \( \vec{F}_1 \) is a unit vector along the positive x-axis, so \( \vec{F}_1 = \hat{i} \). The vector \( \vec{F}_2 \) must have components in both \( i \) and \( j \)-directions to be parallel to \( \hat{i} \), and its magnitude must be 4. The correct vector that satisfies this condition is:
\[
\vec{F}_2 = 2 \hat{i} + 2\sqrt{3} \hat{j}
\]
Step 3: Conclusion.
Thus, \( \vec{F}_2 \) is \( 2 \hat{i} + 2\sqrt{3} \hat{j} \), corresponding to option (C).