The peak flow ordinate of the one-hour unit hydrograph can be determined by first calculating the excess flow, which is the total streamflow minus the baseflow. The peak excess flow in the hydrograph is the maximum value reached after accounting for baseflow.
The maximum streamflow in the table is 40 m\(^3\)/s, and the baseflow is 10 m\(^3\)/s. Thus, the peak excess flow is:
\[
\text{Peak excess flow} = 40 - 10 = 30 \, \text{m}^3/\text{s}.
\]
Therefore, the peak flow ordinate of the one-hour unit hydrograph is \( \boxed{30} \, \text{m}^3/\text{s} \).