The area of the catchment can be calculated using the formula for the triangular unit hydrograph, which is given by:
\[
\text{Area of catchment} = \frac{\text{Peak discharge} \times \text{Base width}}{\text{Rainfall excess}}.
\]
Substituting the given values:
\[
\text{Area of catchment} = \frac{23 \, \text{m}^3/\text{s} \times 144 \, \text{hours}}{1 \, \text{cm}} = 595.2 \, \text{km}^2.
\]
Thus, the area of the catchment is \( \boxed{595} \, \text{km}^2 \).