The first law of thermodynamics states that:
\( \Delta Q = \Delta U + \Delta W \)
We can also express this in terms of rates as:
\( \frac{dQ}{dt} = \frac{dU}{dt} + \frac{dW}{dt} \)
We are given the rate of heat transfer to the system as \( \frac{dQ}{dt} = 1000 \, \text{W} \) and the rate of work done by the system as \( \frac{dW}{dt} = 200 \, \text{W} \). Substituting these values into the equation:
\( 1000 \, \text{W} = \frac{dU}{dt} + 200 \, \text{W} \)
Rearrange the equation to solve for the rate of change of internal energy:
\( \frac{dU}{dt} = 1000 \, \text{W} - 200 \, \text{W} = 800 \, \text{W} \)
The rate at which the internal energy of the system increases is 800 W (Option 3).
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,



What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)