
The question involves two isobaric processes for the same mass of an ideal gas as depicted in the graph, where the x-axis represents temperature (\( T \)) and the y-axis represents volume (\( V \)). In isobaric processes, the pressure is constant, but the temperature and volume can change.
From the given graph, the lines \( P_1 \) and \( P_2 \) represent two different isobaric conditions, starting from the origin \( O \). The slope of each line in a \( V-T \) diagram represents the relationship between \( V \) and \( T \) under constant pressure. The steeper the slope, the lower the pressure.
Thus, the correct relationship is \( P_1 > P_2 \), making option \( P_1 > P_2 \) the correct answer.
From the ideal gas law:
\[ PV = nRT \]
Rearranging for volume:
\[ V = \left( \frac{nR}{P} \right) T \]
The slope of the line in the \( V-T \) graph for an isobaric process is proportional to \( \frac{1}{P} \). Therefore, we have:
\[ \text{Slope} \propto \frac{1}{P} \]
Comparing slopes:\[ (\text{Slope})_2 > (\text{Slope})_1 \quad \implies \quad P_2 < P_1 \]
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,



What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)