To find the work done by the gas during adiabatic expansion, we will use the following principle of adiabatic processes: For adiabatic processes, the formula that relates initial and final states is given by:
\[ PV^\gamma = \text{constant} \]
where \( \gamma \) is the adiabatic constant, here being \( \frac{3}{2} \).
We will consider the initial and final states and the principle that in adiabatic processes, \( PV^\gamma = \text{constant} \).
Suppose the initial volume is \( V \) and the initial pressure is \( P \). After expansion, the final volume is \( 2V \) (since the volume is doubled). Let the final pressure be \( P' \).
By using the adiabatic condition:
\[ P \cdot V^\gamma = P' \cdot (2V)^\gamma \]
Simplifying further,
\[ P = P' \cdot 2^\gamma \]
Substitute \( \gamma = \frac{3}{2} \):
\[ P = P' \cdot 2^{\frac{3}{2}} \]
The work done \( W \) in an adiabatic process is given by:
\[ W = \frac{P_1V_1 - P_2V_2}{\gamma - 1} \]
Substituting \( \gamma \) and rearranging terms, we get:
\[ W = \frac{P \cdot V - P \cdot 2^{-\frac{1}{2}} \cdot 2V}{\frac{3}{2} - 1} \]
Simplifying the expression:
\[ W = \frac{P \cdot V (1 - \sqrt{2})}{\frac{1}{2}} = 2P \cdot V (1 - \sqrt{2}) \]
Using the ideal gas law, \( PV = nRT \), where \( n = 1 \) mole:
\[ W = 2 \cdot (RT) \cdot (1 - \sqrt{2}) \]
Thus, the work done by the gas in the process is:
\[ W = RT[2 - \sqrt{2}] \]
Therefore, the correct option is: \(RT[2 - \sqrt{2}]\).
Step 1: Adiabatic condition The adiabatic condition is given by:
\(TV^{\gamma-1} = \text{constant.}\)
For the initial and final states:
\(T(V)^{\frac{3}{2}-1} = T_f(2V)^{\frac{3}{2}-1}.\)
Simplify:
\(TV^{\frac{1}{2}} = T_f(2V)^{\frac{1}{2}},\)
\(TV\sqrt{V} = T_f\sqrt{2V}.\)
Cancel \(\sqrt{V}\):
\(T = T_f\sqrt{2}.\)
Solve for \(T_f\):
\(T_f = \frac{T}{\sqrt{2}}.\)
Step 2: Work done in adiabatic expansion The work done in an adiabatic process is given by:
\(W.D. = \frac{nR}{1-\gamma}\left[T_f - T\right].\)
Substitute \(T_f = \frac{T}{\sqrt{2}}, \gamma = \frac{3}{2},\) and \(n = 1\):
\(W.D. = \frac{R}{1-\frac{3}{2}}\left[\frac{T}{\sqrt{2}} - T\right].\)
Simplify:
\(W.D. = \frac{R}{-\frac{1}{2}}\left[\frac{T}{\sqrt{2}} - T\right],\)
\(W.D. = -2R\left[\frac{T}{\sqrt{2}} - T\right].\)
Factorize:
\(W.D. = 2RT\left[1 - \frac{1}{\sqrt{2}}\right].\)
Simplify further:
\(W.D. = RT\left[2 - \sqrt{2}\right].\)
Final Answer: \(RT\left[2 - \sqrt{2}\right].\)
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,




What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)