For \(PV^{3/2} = \text{constant}\), we know that:
\[ W = \int P \, dV \]
Since \(P = \frac{K}{V^{3/2}}\):
\[ W = \int_{V_1}^{V_2} \frac{K}{V^{3/2}} \, dV \]
Integrating, we get:
\[ W = \left[ -\frac{2K}{V^{1/2}} \right]_{V_1}^{V_2} = 2(P_1V_1 - P_2V_2) \]
- If the work done by the gas is asked:
\[ W = 2(P_1V_1 - P_2V_2) \quad \text{(Option 1)} \]
- If the work done on the gas (by external) is asked:
\[ W = 2(P_2V_2 - P_1V_1) \quad \text{(Option 2)} \]
The pressure and volume of an ideal gas are related as \( PV^{3/2} = K \) (constant). We need to find the work done when the gas is taken from state A (\( P_1, V_1, T_1 \)) to state B (\( P_2, V_2, T_2 \)).
For a thermodynamic process, the work done by the gas is given by:
\[ W = \int_{V_1}^{V_2} P \, dV \]
Given the process follows \( PV^{3/2} = K \), we can substitute \( P = \frac{K}{V^{3/2}} \) into the integral and evaluate it.
Step 1: Write the work done integral using the given polytropic relation \( PV^{3/2} = K \).
\[ W = \int_{V_1}^{V_2} P \, dV = \int_{V_1}^{V_2} \frac{K}{V^{3/2}} \, dV \]
Step 2: Factor out the constant \( K \) and integrate.
\[ W = K \int_{V_1}^{V_2} V^{-3/2} \, dV \] \[ W = K \left[ \frac{V^{-3/2 + 1}}{-3/2 + 1} \right]_{V_1}^{V_2} = K \left[ \frac{V^{-1/2}}{-1/2} \right]_{V_1}^{V_2} \] \[ W = -2K \left[ V^{-1/2} \right]_{V_1}^{V_2} = -2K \left( \frac{1}{\sqrt{V_2}} - \frac{1}{\sqrt{V_1}} \right) \] \[ W = 2K \left( \frac{1}{\sqrt{V_1}} - \frac{1}{\sqrt{V_2}} \right) \]
Step 3: Express the constant \( K \) in terms of initial state parameters \( P_1 \) and \( V_1 \). Since \( K = P_1 V_1^{3/2} \), substitute this into the expression.
\[ W = 2 (P_1 V_1^{3/2}) \left( \frac{1}{\sqrt{V_1}} - \frac{1}{\sqrt{V_2}} \right) \] \[ W = 2 P_1 V_1^{3/2} \left( V_1^{-1/2} - V_2^{-1/2} \right) \] \[ W = 2 P_1 V_1 \left( 1 - \frac{\sqrt{V_1}}{\sqrt{V_2}} \right) \]
Step 4: Also express \( K \) in terms of final state parameters \( P_2 \) and \( V_2 \) to find a symmetric form. Since \( K = P_1 V_1^{3/2} = P_2 V_2^{3/2} \), we can write the work done as:
\[ W = 2K \left( \frac{1}{\sqrt{V_1}} - \frac{1}{\sqrt{V_2}} \right) = 2 \left( \frac{K}{\sqrt{V_1}} - \frac{K}{\sqrt{V_2}} \right) \] \[ W = 2 \left( \frac{P_1 V_1^{3/2}}{\sqrt{V_1}} - \frac{P_2 V_2^{3/2}}{\sqrt{V_2}} \right) \] \[ W = 2 \left( P_1 V_1 - P_2 V_2 \right) \]
Thus, the work done by the gas is \( 2(P_1V_1 - P_2V_2) \).
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,




Given below are two statements:
Statement 1: If a capillary tube is immersed first in cold water and then in hot water, the height of capillary rise will be smaller in hot water.
Statement 2: If a capillary tube is immersed first in cold water and then in hot water, the height of capillary rise will be smaller in cold water.
In the light of the above statements, choose the most appropriate option from the options given below:
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)