Step 1: Brewster law
At the polarising angle, \(\tan\Phi=\mu\), and \(\Phi+r=90^{\circ}\).
Step 2: Angle between rays
The reflected ray makes \(\Phi\) with the normal and the refracted ray makes \(r=90^{\circ}-\Phi\). The angle between them is \(180^{\circ}-\Phi-r=90^{\circ}\). Option (B).
Final Answer:
The angle is \(90^{\circ}\), option (B).
\[ \boxed{\text{(B) }90^{\circ}} \]