Step 1: Understanding the Concept
Radioactive decay is a first order process. The half-life is \(t_{1/2} = \dfrac{0.693}{\lambda}\). After every half-life the amount left is halved.
Step 2: Calculation of half-life
\(t_{1/2} = \dfrac{0.693}{0.1} = 6.93\) years.
Step 3: Number of half-lives
\(n = \dfrac{13.86}{6.93} = 2\).
Step 4: Amount left and decayed
Fraction left \(= \left(\dfrac{1}{2}\right)^{2} = \dfrac{1}{4}\), that is 25%.
So the decayed fraction is \(100 - 25 = 75\%\).
Final Answer:
75% of the substance decays in 13.86 years.
\[ \boxed{\text{(C) }75} \]