To determine the maximum fractional error in the quantity \(Q\), we will need to consider how the errors in parameters \(X\), \(Y\), and \(Z\) propagate through the equation. The given quantity is:
\(Q = X^{-2} Y^{3/2} Z^{-2/5}\)
The fractional error of a product or quotient can be found by taking the partial derivative with respect to each variable, multiplying by the corresponding fractional error, and summing the absolute values of these terms:
The general formula for fractional error in a multiplicative relationship \(Q = X^a Y^b Z^c\) is:
\(\frac{\Delta Q}{Q} = |a| \frac{\Delta X}{X} + |b| \frac{\Delta Y}{Y} + |c| \frac{\Delta Z}{Z}\)
For the given function \(Q = X^{-2} Y^{3/2} Z^{-2/5}\), the exponents are \(a = -2\), \(b = \frac{3}{2}\), and \(c = -\frac{2}{5}\).
Given the fractional errors:
Using the formula for fractional error, we find:
\(\frac{\Delta Q}{Q} = |-2| \times 0.1 + \left|\frac{3}{2}\right| \times 0.2 + \left|-\frac{2}{5}\right| \times 0.5\)
Calculating each term:
Therefore, the maximum fractional error of \(Q\) is 0.7.
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,

What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)