Step 1: Identify the type of semiconductor.
The semiconductor is doped with pentavalent impurity atoms.
Pentavalent impurities are donor impurities, so the semiconductor becomes an \(n\)-type semiconductor.
In an \(n\)-type semiconductor, electrons are majority carriers and holes are minority carriers.
Step 2: Calculate donor concentration.
Total number of atoms in the pure semiconductor is
\[
8\times10^{28}\ \text{m}^{-3}.
\]
Doping concentration is
\[
2\ \text{ppm}=2\times10^{-6}.
\]
Therefore, donor concentration is
\[
N_D=(8\times10^{28})(2\times10^{-6}).
\]
\[
N_D=16\times10^{22}.
\]
\[
N_D=1.6\times10^{23}\ \text{m}^{-3}.
\]
For an \(n\)-type semiconductor,
\[
n\approx N_D.
\]
So,
\[
n=1.6\times10^{23}\ \text{m}^{-3}.
\]
Step 3: Use mass action law.
For a semiconductor,
\[
np=n_i^2,
\]
where \(n\) is electron concentration, \(p\) is hole concentration, and \(n_i\) is intrinsic carrier concentration.
Therefore,
\[
p=\frac{n_i^2}{n}.
\]
Given,
\[
n_i=1\times10^{16}\ \text{m}^{-3}.
\]
Thus,
\[
p=\frac{(1\times10^{16})^2}{1.6\times10^{23}}.
\]
\[
p=\frac{1\times10^{32}}{1.6\times10^{23}}.
\]
\[
p=0.625\times10^9.
\]
\[
p=6.25\times10^8\ \text{m}^{-3}.
\]
Step 4: Final conclusion.
Therefore, the number of holes formed in the semiconductor crystal is
\[
\boxed{6.25\times10^8\ \text{m}^{-3}}
\]
Hence, the correct option is
\[
\boxed{(2)}
\]