Step 1: Understanding the Concept:
In a potentiometer, the potential drop is uniform along the wire. The emf of a cell is the potential drop over the balancing length.
Step 2: Potential gradient.
\[ k = \frac{3\text{ V}}{4\text{ m}} = 0.75\text{ V/m} \]
Step 3: EMF.
Balancing length \(l = 100\) cm \(= 1\) m.
\[ E = k\,l = 0.75\times 1 = 0.75\text{ V} \]
Step 4: Check the options.
0.25 V would result from using 1/12 of the wire, and 1.0 V from using 4/3 m. Only 0.75 V fits.
Final Answer:
The emf of the cell is 0.75 V, option (C).
\[ \boxed{0.75\text{ V}} \]