Given:
\[ \vec{P}(t) = \cos(kt) \, \hat{i} - \sin(kt) \, \hat{j}, \quad |\vec{P}| = 1. \]
The linear momentum \( \vec{P} \) is given by:
\[ \vec{P} = m\vec{v} \implies \hat{P} = \vec{v}, \]
where \( \hat{P} \) is the unit vector in the direction of \( \vec{P} \).
Step 1: Calculating the Velocity Vector
Differentiating \( \vec{P}(t) \) with respect to time to find the velocity vector:
\[ \vec{v} = \frac{d\vec{P}}{dt} = -k\sin(kt) \, \hat{i} - k\cos(kt) \, \hat{j}. \]
The acceleration vector \( \vec{a} \) is given by:
\[ \vec{a} = \frac{d\vec{v}}{dt} = -k^2\cos(kt) \, \hat{i} + k^2\sin(kt) \, \hat{j}. \]
Step 2: Calculating the Angle Between \( \vec{F} \) and \( \vec{P} \)
The force \( \vec{F} \) is given by Newton’s second law:
\[ \vec{F} = m\vec{a}. \]
To find the angle \( \theta \) between \( \vec{F} \) and \( \vec{P} \), we use the dot product:
\[ \cos\theta = \frac{\vec{F} \cdot \vec{P}}{|\vec{F}||\vec{P}|}. \]
Substituting the expressions for \( \vec{F} \) and \( \vec{P} \):
\[ \vec{F} \cdot \vec{P} = (-k^2\cos(kt))\cos(kt) + (k^2\sin(kt))\sin(kt) = -k^2(\cos^2(kt) + \sin^2(kt)) = -k^2. \]
Since \( |\vec{F}| = k^2 \) and \( |\vec{P}| = 1 \), we have:
\[ \cos\theta = \frac{-k^2}{k^2} = -1 \implies \theta = \frac{\pi}{2}. \]
Therefore, the angle between \( \vec{F} \) and \( \vec{P} \) is \( \frac{\pi}{2} \).
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,

What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)