Step 1: Use de Broglie wavelength for electrons.
\[
\lambda = \frac{h}{p} = \frac{h}{mv}
\]
Step 2: Effect of increasing speed.
If \(v\) increases, momentum \(p=mv\) increases, so de Broglie wavelength decreases:
\[
v \uparrow \Rightarrow \lambda \downarrow
\]
Step 3: Diffraction angular width relation.
For single slit diffraction:
\[
\theta \approx \frac{\lambda}{a}
\]
So if \(\lambda\) decreases, \(\theta\) decreases.
Step 4: Conclusion.
Thus, the angular width of central maximum decreases when electron speed increases.
Final Answer:
\[
\boxed{\text{(C) angular width decreases}}
\]