The problem asks for the change in temperature of a gas that is adiabatically compressed from an initial volume and temperature to a final volume. The container has thermally non-conducting walls, which confirms the process is adiabatic.
For a reversible adiabatic process, the relationship between the absolute temperature (T) and volume (V) of a gas is given by the equation:
\[ TV^{\gamma-1} = \text{constant} \]where \( \gamma \) is the ratio of specific heats (\( C_p/C_v \)). For two states, initial (1) and final (2), this relationship can be written as:
\[ T_1 V_1^{\gamma-1} = T_2 V_2^{\gamma-1} \]Step 1: List the given initial and final state variables and convert the temperature to Kelvin.
Given values are:
In thermodynamics, we must use the absolute temperature scale (Kelvin). The conversion is \( T(\text{K}) = T(^\circ\text{C}) + 273 \).
\[ T_1 = 27 + 273 = 300 \, \text{K} \]Step 2: Set up the adiabatic relation to find the final temperature \( T_2 \).
Using the relation \( T_1 V_1^{\gamma-1} = T_2 V_2^{\gamma-1} \), we can solve for \( T_2 \):
\[ T_2 = T_1 \left( \frac{V_1}{V_2} \right)^{\gamma-1} \]Step 3: Substitute the given values into the equation and calculate \( T_2 \).
First, calculate the exponent \( \gamma - 1 \):
\[ \gamma - 1 = 1.5 - 1 = 0.5 = \frac{1}{2} \]Next, calculate the ratio of the volumes:
\[ \frac{V_1}{V_2} = \frac{800 \, \text{cm}^3}{200 \, \text{cm}^3} = 4 \]Now, substitute these values into the equation for \( T_2 \):
\[ T_2 = 300 \, \text{K} \times (4)^{0.5} = 300 \, \text{K} \times \sqrt{4} \] \[ T_2 = 300 \, \text{K} \times 2 = 600 \, \text{K} \]The question asks for the change in temperature, which is \( \Delta T = T_2 - T_1 \).
\[ \Delta T = 600 \, \text{K} - 300 \, \text{K} = 300 \, \text{K} \]The change in temperature is 300 K. This corresponds to option (4).
\( V_1 = 800 cm^3 \) \( V_2 = 200 cm^3 \) \( T_1 = 300 \)
K For adiabatic: \( TV^{\gamma - 1} = \) constant.
\( T_1 V_1^{\gamma - 1} = T_2 V_2^{\gamma - 1} \) \( (300) (800)^{1.5 - 1} = T_2 (200)^{1.5 - 1} \) \( T_2 = 300 \left( \frac{800}{200} \right)^{0.5} \) \( T_2 = 300 (4)^{1/2} \)
\( T_2 = 600 \) K \( \Delta T = 600 - 300 = 300 \) K
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,



What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)