Step 1: Apply Chargaff’s rule.
In double-stranded DNA:
\[
\text{A} = \text{T}, \quad \text{G} = \text{C}, \quad \text{and} \quad (\text{A} + \text{T}) + (\text{G} + \text{C}) = 100%
\]
Step 2: Given.
A = 32 mol% ⇒ T = 32 mol%.
\[
\text{A} + \text{T} = 64%
\]
Step 3: Find (G + C).
\[
100 - 64 = 36%
\]
Since G = C,
\[
\text{C} = 18%, \quad \text{G} = 18%
\]
Step 4: Conclusion.
\[
\boxed{\text{Cytosine (C)} = 18~\text{mol%}}
\]