Concept:
Conditional probability:
\[
P(A|B) = \frac{\text{favourable outcomes}}{\text{total outcomes}}
\]
Step 1: Fix first throw.
\[
\text{First number} = 5
\]
Remaining sum needed:
\[
14 - 5 = 9
\]
Step 2: Find combinations.
Possible pairs:
\[
(3,6), (4,5), (5,4), (6,3)
\Rightarrow 4 \text{ outcomes}
\]
Step 3: Total possible outcomes.
\[
6 \times 6 = 36
\]
Step 4: Compute probability.
\[
\frac{4}{36} = \frac{1}{9}
\]