Step 1: Understand which cube has zero painted faces.
A small cube shows a painted face only if it sits on the outer surface of the big cube. A small cube with no painted face at all must be completely buried inside, with none of its 6 faces touching the outside.
Step 2: Use the standard formula.
When a cube is cut into \(n\) equal parts along each edge, the number of completely inside (fully unpainted) small cubes is given by
\[ (n-2)^3 \]
because you remove one layer of small cubes from each side of the cube along every direction, leaving an inner cube of side \(n-2\).
Step 3: Substitute the value.
Here \(n = 3\), so
\[ (3-2)^3 = 1^3 = 1 \]
This single unpainted cube is the exact centre of the big cube, the one small cube that does not touch any of the 6 outer faces.
Final Answer:
Only 1 smaller cube has no face painted.
\[ \boxed{1} \]