Step 1: Set up coordinates.
Label each unit cube by its position (x, y, z), with x, y, z each running from 1 to 7 along the three edges of the big cube. The three painted faces are the three outer faces, say x = 7, y = 7 and z = 7 (the three faces visible from inside the room).
Step 2: Understanding the Concept.
A unit cube gets paint on a face only if it sits on one of these three outer layers. A unit cube has zero painted faces only if none of its coordinates touch 7, meaning x, y and z must each be chosen from 1 to 6.
Step 3: Count the unpainted cubes.
There are 6 valid choices for x, 6 for y and 6 for z, so the count is \(6\times6\times6=216\).
Step 4: Final Answer.
216 of the smaller cubes have no paint on them at all, so option D is correct.