In \(KMnO_4\), manganese is in +7 oxidation state.
Electronic configuration of \(Mn^{7+}\):
\[
3d^0
\]
Since there are no unpaired electrons:
\[
\text{diamagnetic}
\]
Also, permanganate ion is intensely coloured due to charge transfer transitions.
Hence, the correct answer is:
\[
\boxed{(C)\ KMnO_4}
\]