The volume of 1000 small drops is equal to the volume of the big drop:

\[ 1000 \times \frac{4}{3}\pi r^3 = \frac{4}{3}\pi R^3 \]
\[ R = 10r \]
The surface energy (S.E.) of the 1000 drops is:
\[ \text{S.E. of 1000 drops} = 1000 \times (4\pi r^2)T \]
The surface energy of the big drop is:
\[ \text{S.E. of Big drop} = 4\pi R^2T \]
Substituting \( R = 10r \):
\[ \text{S.E. of Big drop} = 4\pi (10r)^2T = 400\pi r^2T \]
The ratio of the surface energy is:
\[ \frac{\text{S.E. of 1000 drops}}{\text{S.E. of Big drop}} = \frac{1000 \cdot 4\pi r^2T}{4\pi (10r)^2T} \]
\[ \frac{\text{S.E. of 1000 drops}}{\text{S.E. of Big drop}} = \frac{1000}{100} = \frac{10}{x} \]
\[ x = 1 \]
To solve this problem, we consider the concept of surface energy related to the surface area of spherical droplets.
Given:
1. 1000 small droplets coalesce to form one big drop.
2. The ratio of surface energy of the 1000 droplets to the big drop is \( \frac{10}{x} \).
Step 1: Surface area of the droplets
If each small droplet has radius \( r \), the surface area \( A \) of one droplet is \( A = 4\pi r^2 \).
Total surface area for 1000 droplets is \( 1000 \times 4\pi r^2 = 4000\pi r^2 \).
Step 2: Surface area of the big drop
The volume of all droplets combined forms the big drop. Volume of one small droplet is \( \frac{4}{3}\pi r^3 \). So, total volume of 1000 small droplets is \( 1000 \times \frac{4}{3}\pi r^3 = \frac{4000}{3}\pi r^3 \).
Let the radius of the big drop be \( R \). Equating volumes:
\( \frac{4}{3}\pi R^3 = \frac{4000}{3}\pi r^3 \) gives \( R^3 = 1000r^3 \) or \( R = 10r \).
The surface area of the big drop is \( 4\pi R^2 = 4\pi (10r)^2 = 400\pi r^2 \).
Step 3: Calculate surface energy ratio
Assuming surface tension is constant, and given surface energy is proportional to surface area:
Ratio of surface energies = \( \frac{4000\pi r^2}{400\pi r^2} = 10 \).
Set this equal to the given \( \frac{10}{x} \), so \( 10 = \frac{10}{x} \), which gives \( x = 1 \).
Verification: \( x = 1 \) fits within the range 1 to 1.
Conclusion: \( x \) is confirmed as \( 1 \).
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,



What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)