Step 1: Understanding the relation.
The concentration (molarity) of a solution is given by the formula:
\[
\text{Molarity} = \frac{\text{Number of moles}}{\text{Volume in Liters}}
\]
First, calculate the number of moles of glucose using Avogadro's number:
\[
\text{Number of moles} = \frac{6.022 \times 10^{23}}{6.022 \times 10^{23}} = 1 \, \text{mol}
\]
Now, convert the volume of the solution into liters:
\[
\text{Volume in Liters} = \frac{100}{1000} = 0.1 \, \text{L}
\]
Step 2: Calculating the molarity.
\[
\text{Molarity} = \frac{1 \, \text{mol}}{0.1 \, \text{L}} = 0.1 \, \text{M}
\]
Step 3: Conclusion.
The correct answer is (B) 0.1 M, the molarity of the solution.