Atomic and Ionic Size: Across a period, atomic size slightly decreases due to poor shielding by d-electrons. Down a group, size increases due to the addition of a new energy level.
Ionization Enthalpy: Transition metals have higher ionization enthalpy due to their small size and nuclear attraction. \item Ionization energy does not increase significantly across the series because of screening effects.
(i) Draw the diagram which indicates the splitting of d-orbitals in tetrahedral field.
(ii) Write any one limitation of valence bond theory.
(i)[Ni(CN)₄]²⁻ and [Ni(CO)(_4)] have different structures, but do not differ in their magnetic behaviour. Explain.
(ii) Write the formula of Tetraamineaquachloridocobalt(III)chloride.
(i) Write two postulates of Werner's coordination theory.
(ii) Draw the geometrical isomers of [(NH_3)_3(NO_2)_3] and give their structures.