Step 1: Understanding Wilkinson's catalyst.
Wilkinson's catalyst is a well-known catalyst used in organic chemistry, specifically for the hydrogenation of alkenes. The catalyst consists of rhodium in a square planar coordination environment, with a chloride and phosphine ligands attached.
Step 2: Conclusion.
Wilkinson's catalyst contains rhodium(I) in a square planar geometry.
Final Answer:
\[
\boxed{\text{Rhodium(I) in square planar geometry.}}
\]