Which reagent gives bright red ppt. With \(Ni^{2+}\) in basic medium?
- \(DMG\)
- \(Nessler's \;Reagent\)
- \(KCNS\)
- \(K_4[Fe(CN)_6]\)
The Correct Option is A
Solution and Explanation
The correct option is (A): \(DMG\)
Top Questions on reaction mechanism
- Given below are two statements:
Statement I: The dipole moment of R–CN is greater than R–NC and R–NC can undergo hydrolysis under acidic medium to produce R–COOH.
Statement II: R–CN hydrolyses under acidic medium to produce a compound which on treatment with SOCl$_2$, followed by the addition of NH$_3$ gives another compound (X). This compound (X) on treatment with NaOCl/NaOH gives a product, that on treatment with CHCl$_3$/KOH/$\Delta$ produces R–NC.
In the light of the above statements, choose the correct answer from the options given below.
- JEE Main - 2026
- Chemistry
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- Given below are two statements:
Statement I: Phenol on treatment with \( \mathrm{CHCl_3/aq.\ KOH} \) under refluxing condition, followed by acidification produces p-hydroxy benzaldehyde as the major product and o-hydroxy benzaldehyde as the minor product.
Statement II: The mixture of p-hydroxybenzaldehyde and o-hydroxybenzaldehyde can be easily separated through steam distillation.
In the light of the above statements, choose the correct answer from the options given below- JEE Main - 2026
- Chemistry
- reaction mechanism
The correct order of the rate of reaction of the following reactants with nucleophile by \( \mathrm{S_N1} \) mechanism is:
(Given: Structures I and II are rigid)
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- Chemistry
- reaction mechanism
- Given below are two statements:
Statement I: Propene on treatment with diborane gives an addition product with the formula \(((\text{CH}_3)_2 - \text{CH}_3\text{B})\).
Statement II: Oxidation of \(((\text{CH}_3)_2 - \text{CH}_3\text{B})\) with hydrogen peroxide in presence of NaOH gives propan-2-ol.
In the light of the above statements, choose the most appropriate answer from the options given below:- NEET (UG) - 2024
- Chemistry
- reaction mechanism
- Best reducing agent among the given ions are:
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- Chemistry
- reaction mechanism
Questions Asked in JEE Main exam
- Identify the correct statements: The presence of –NO\(_2\) group in benzene ring A. activates the ring towards electrophilic substitutions. B. deactivates the ring towards electrophilic substitutions. C. activates the ring towards nucleophilic substitutions. D. deactivates the ring towards nucleophilic substitutions. Choose the correct answer from the options given below:
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- General Chemistry
- Let $\vec{a}=2\hat{i}-\hat{j}-\hat{k}$, $\vec{b}=\hat{i}+3\hat{j}-\hat{k}$ and $\vec{c}=2\hat{i}+\hat{j}+3\hat{k}$. Let $\vec{v}$ be the vector in the plane of $\vec{a}$ and $\vec{b}$, such that the length of its projection on the vector $\vec{c}$ is $\dfrac{1}{\sqrt{14}}$. Then $|\vec{v}|$ is equal to
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- Vector Algebra
A substance 'X' (1.5 g) dissolved in 150 g of a solvent 'Y' (molar mass = 300 g mol$^{-1}$) led to an elevation of the boiling point by 0.5 K. The relative lowering in the vapour pressure of the solvent 'Y' is $____________ \(\times 10^{-2}\). (nearest integer)
[Given : $K_{b}$ of the solvent = 5.0 K kg mol$^{-1}$]
Assume the solution to be dilute and no association or dissociation of X takes place in solution.- JEE Main - 2026
- Solutions
- The wavelength of photon 'A' is 400 nm. The frequency of photon 'B' is \(10^{16}\,\text{s}^{-1}\). The wave number of photon 'C' is \(10^{5}\,\text{cm}^{-1}\). The correct order of energy of these photons is:
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- General Chemistry
- Given below are two statements: Statement I: The increasing order of boiling point of hydrogen halides is HCl<HBr<HI<HF. Statement II: The increasing order of melting point of hydrogen halides is HCl<HBr<HF<HI. In the light of the above statements, choose the correct answer from the options given below:
- JEE Main - 2026
- General Chemistry
Concepts Used:
Organic Chemistry – Some Basic Principles and Techniques - Reaction Mechanism
SN1 Reaction Mechanism:
SN1 reaction mechanism takes place by following three steps –
- Formation of carbocation
- Attack of nucleophile
- Deprotonation
SN2 Reaction Mechanism:
The SN2 reaction mechanism involves the nucleophilic substitution reaction of the leaving group (which generally consists of halide groups or other electron-withdrawing groups) with a nucleophile in a given organic compound.
Electrophilic Aromatic Substitution Reaction Mechanism:
The mechanism of an electrophilic aromatic substitution reaction contains three main components which are:
- A new sigma bond from C=C is formed during the reaction in the arene nucleophile.
- Due to the breaking of the C-H sigma bond, a proton is removed.
- The C=C bond is reformed and it restores the aromaticity of the compound.
Electrophilic Substitution Reaction Mechanism:
The electrophilic substitution reaction mechanism is composed of three steps, which will be discussed more below.
- Electrophile Generation
- Carbocation Formation
- Proton Removal