Remember: The higher the oxidation state of a metal in its oxide, the more acidic the oxide is. Mn\textsuperscript{+7} in Mn\textsubscript{2}O\textsubscript{7} makes it a highly acidic oxide.
Step 1: Understand oxidation states and oxide nature
Oxides of elements, particularly transition metals like manganese, can exhibit varying acid-base properties depending on the oxidation state:
Lower oxidation states ⇒ Basic or amphoteric oxides
Higher oxidation states ⇒ More acidic oxides
Step 2: Assign oxidation states to given compounds
MnO: Mn is in +2 oxidation state ⇒ basic oxide
Mn2O3: Mn is in +3 oxidation state ⇒ weakly basic/amphoteric
MnO2: Mn is in +4 oxidation state ⇒ amphoteric
Mn2O7: Mn is in +7 oxidation state ⇒ strongly acidic
Step 3: Conclusion
Mn2O7 has the highest oxidation state of +7 for manganese. Hence, it is the most acidic oxide among the options given.
\[
\boxed{\text{Mn}_2\text{O}_7 \text{ is the most acidic oxide}}
\]