Question:

Which one of the following is the structure of polyacrylonitrile?

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In addition polymers, substituent of monomer appears on alternate carbon.
Updated On: Apr 23, 2026
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The Correct Option is B

Solution and Explanation

Concept: Addition polymerisation of vinyl monomers.

Step 1:
Monomer of PAN = CH$_2$=CH–CN (acrylonitrile).

Step 2:
In addition polymerisation, double bond breaks and forms backbone.

Step 3:
Polymer structure becomes [-CH$_2$–CH(CN)-]$_n$.

Step 4:
CN group remains as side substituent on chain.
Conclusion:
Correct structure = option (B)
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