Question:

Which of the following represents octahedral interstitial site in an FCC lattice?

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FCC has 4 octahedral and 8 tetrahedral voids per unit cell.
Updated On: Jun 29, 2026
  • $(\frac{1}{4},\frac{1}{4},\frac{1}{4})$
  • $(\frac{1}{2},\frac{1}{2},\frac{1}{2})$
  • $(\frac{1}{3},\frac{1}{3},\frac{1}{3})$
  • (0,0,0)
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The Correct Option is B

Solution and Explanation

Concept: In FCC crystals:
• Octahedral sites are located at the center of the unit cell and edge centers
• Tetrahedral sites are located at $(\frac{1}{4},\frac{1}{4},\frac{1}{4})$

Step 1:
Identify octahedral site.
The body center position: \[ \left(\frac{1}{2},\frac{1}{2},\frac{1}{2}\right) \] is a classic octahedral interstitial position in FCC.

Step 2:
Differentiate from tetrahedral site.

• $(\frac{1}{4},\frac{1}{4},\frac{1}{4})$ → tetrahedral site
• $(\frac{1}{2},\frac{1}{2},\frac{1}{2})$ → octahedral site Final Answer: \[ \boxed{\left(\frac{1}{2},\frac{1}{2},\frac{1}{2}\right)} \]
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