Concept:
In metallography, the microstructure of a material cannot be observed directly on a mirror-polished surface. It must be revealed using selective chemical attack, known as etching.
Etching highlights grain boundaries and different phases by differential chemical reactivity.
Step 1: Purpose of surface preparation.
Before etching:
• grinding removes surface irregularities
• polishing produces a smooth mirror-like finish
• buffing improves surface smoothness further
However, none of these reveal microstructure.
Step 2: Role of etching.
Etching:
• attacks different phases at different rates
• reveals grain boundaries
• makes microstructural features visible under microscope
Step 3: Why others are incorrect.
• Grinding → only leveling
• Polishing → smooth surface only
• Buffing → final finishing step
None of these expose microstructure.
Final Answer:
\[
\boxed{\text{Etching}}
\]