Concept:
Primary fuels are obtained directly from nature. Secondary fuels are obtained by processing primary fuels.
Step 1: Wood is obtained directly from nature, so it is a primary fuel.
Step 2: Petroleum is obtained naturally from the earth, so it is a primary fuel.
Step 3: Coal is also obtained naturally, so it is a primary fuel.
Step 4: Coke is obtained by destructive distillation of coal.
So coke is not a primary fuel; it is a secondary fuel.
Therefore,
\[
\boxed{\text{Coke}}
\]