Question:

Which law of size reduction is applicable when the surface area of particles is more important than size?

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Logic Tip: Use this memory trick: Coarse = Kick's, Intermediate = Bond's, Fine (Surface Area) = Rittinger's.
  • Kick's law
  • Rittinger's law
  • Bond's law
  • Newton's law
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The Correct Option is B

Solution and Explanation

Concept:
In mechanical size reduction (comminution), different empirical laws are used to estimate the energy required depending on the starting and ending sizes of the particles.

Step 1:
Kick's law states that the energy required is proportional to the ratio of the initial and final sizes (volume). It is most accurate for coarse crushing.

Step 2:
Bond's law is an intermediate law that states energy is proportional to the square root of the surface-to-volume ratio. It is used for intermediate grinding.

Step 3:
Rittinger's law postulates that the energy required for size reduction is directly proportional to the new surface area created during the milling process.

Step 4:
When fine grinding is performed, a massive amount of new surface area is generated. Because Rittinger's law is fundamentally based on surface area creation, it is the applicable law for this scenario.
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