Which among the following is paramagnetic?
A species with one or more unpaired electrons is paramagnetic.
A species with one or more unpaired electrons is paramagnetic.
No. of valence electrons in Cl2O = 7 x 2 + 6 = 20 (even)
No. of valence electrons in ClO2 = 7 + 6 x 2 = 19 (odd)
No. of valence electrons in Cl2O7 = 7 x 2 + 6 x 7 = 56 (even)
No. of valence electrons in Cl2O6 = 7 x 2 + 6 x 6 = 50 (even)
Thus, ClO2 is expected to be paramagnetic.
| Column I | Column II | ||
|---|---|---|---|
| (a) | $XX'$ | (i) | T-shape |
| (b) | $XX'_3$ | (ii) | Pentagonal bipyramidal |
| (c) | $XX'_5$ | (iii) | Linear |
| (d) | $XX'_7$ | (iv) | Square-pyramidal |
| (v) | Tetrahedral | ||
| List-I (Oxoacids of Sulphur) | List-II (Bonds) | ||
| A | Peroxodisulphuric acid | I | Two S–OH, Four S=O, One S–O–S |
| B | Sulphuric acid | II | Two S–OH, One S=O |
| C | Pyrosulphuric acid | III | Two S–OH, Four S=O, One S–O–O–S |
| D | Sulphurous acid | IV | Two S–OH, Two S=O |