Question:

When aryl halide is treated with \(Na\) in dry ether, biphenyl is formed. This reaction is called

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Fittig reaction forms biaryl compounds from aryl halides.
Updated On: Apr 24, 2026
  • Fittig reaction
  • Wurtz-Fittig reaction
  • Swarts reaction
  • Williamson’s synthesis
  • Kolbe’s reaction
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The Correct Option is A

Solution and Explanation

Concept: Coupling reactions with sodium metal:

Step 1:
Understand reaction types.

• Wurtz reaction $\rightarrow$ alkyl halides
• Fittig reaction $\rightarrow$ aryl halides
• Wurtz-Fittig $\rightarrow$ alkyl + aryl

Step 2:
Identify given reaction.
\[ \text{Aryl halide} + Na \rightarrow \text{Biphenyl} \]
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