Step 1: Understanding the Concept:
The highest oxidation state of a 3d element is usually the sum of its \(4s\) and \(3d\) electrons.
Step 2: Manganese:
Mn has the configuration \([\text{Ar}]3d^5 4s^2\), which has 7 valence electrons. Removing all of them gives \(+7\), as in \(\text{KMnO}_4\) and \(\text{Mn}_2\text{O}_7\).
Step 3: Check the Other Options:
\(+8\) is not possible because there are only 7 electrons available. \(+5\) and \(+6\) are real states (manganate(V) and manganate(VI) ions), but they are not the highest. So (D) is correct.
Final Answer:
The highest oxidation state of Mn is +7, option (D).
\[ \boxed{\text{(D) } +7} \]