Concept:
For a sector of a circle having radius \(r\) and central angle \(\theta\),
\[
\text{Perimeter of Sector} = 2r + L
\]
where \(L\) is the arc length.
Also,
\[
L=\frac{\theta}{360^\circ}\times 2\pi r
\]
or equivalently,
\[
\theta=\frac{360L}{2\pi r}
\]
To determine the angle subtended at the centre, both the radius and the arc length must be known.
Step 1: Analyze Statement (I) Alone.
Statement (I) states that the perimeter of the sector is 16 units.
\[
2r+L=16
\]
This equation contains two unknowns, namely \(r\) and \(L\).
For example:
\[
r=3,\quad L=10
\]
satisfies the condition.
Also,
\[
r=4,\quad L=8
\]
satisfies the same condition.
Different values of \(r\) and \(L\) produce different central angles.
Therefore, Statement (I) alone is not sufficient.
Step 2: Analyze Statement (II) Alone.
Statement (II) states that the arc length is
\[
L=10
\]
However, the radius is unknown.
For instance,
\[
r=5
\]
and
\[
r=10
\]
both give different central angles for the same arc length.
Thus, Statement (II) alone is also not sufficient.
Step 3: Combine Statements (I) and (II).
From Statement (II),
\[
L=10
\]
Substituting into Statement (I),
\[
2r+10=16
\]
\[
2r=6
\]
\[
r=3
\]
Now both the radius and arc length are known.
Using
\[
L=\frac{\theta}{360^\circ}\times 2\pi r
\]
\[
10=\frac{\theta}{360^\circ}\times 2\pi(3)
\]
\[
10=\frac{\theta}{360^\circ}\times 6\pi
\]
Hence the value of \(\theta\) can be uniquely determined.
Therefore, the two statements together are sufficient.
\[
\boxed{\text{Both statements together are sufficient}}
\]