Concept:
VSEPRT stands for:
\[
\text{Valence Shell Electron Pair Repulsion Theory}
\]
This theory explains:
• Shapes of molecules
• Arrangement of electron pairs
• Bond angles in covalent compounds
According to this theory:
Electron pairs present in the valence shell repel each other and arrange themselves as far apart as possible to minimize repulsion.
The theory was proposed by:
\[
\boxed{\text{Sidgwick and Powell}}
\]
Step 1: Understand the purpose of VSEPR theory.
VSEPR theory helps predict molecular geometry.
Examples:
• \(CH_4\) : Tetrahedral
• \(NH_3\) : Pyramidal
• \(H_2O\) : Bent shape
The shapes arise because electron pairs repel one another.
Step 2: Analyze all options carefully.
Option (A): Linus Pauling
Linus Pauling is famous for:
• Hybridization
• Electronegativity concept
Not VSEPR theory.
Hence incorrect.
Option (B): Moseley and Mendeleev
Moseley worked on atomic numbers and Mendeleev proposed periodic table.
Not related to VSEPR theory.
Hence incorrect.
Option (C): Lewis and Kossel
They explained chemical bonding concepts and octet theory.
Not VSEPR theory.
Hence incorrect.
Option (D): Sidgwick and Powell
They proposed the VSEPR concept.
Hence this option is correct.
Step 3: Select the correct answer.
Therefore, VSEPRT theory was proposed by:
\[
\boxed{\text{Sidgwick and Powell}}
\]
Hence,
\[
\boxed{(4)\ \text{Sidgwick and Powell}}
\]