Question:

Two statements are given below :
Statement I : The melting point of monocarboxylic acid with even number of carbon atoms is higher than that of with odd number of carbon atoms acid immediately below and above it in the series.
Statement II : The solubility of monocarboxylic acids in water decreases with increase in molar mass.
Choose the most appropriate option :

Show Hint

Both are standard facts about monocarboxylic acids: an alternation effect in melting points and falling water solubility as the hydrocarbon chain lengthens.
Updated On: Nov 4, 2026
  • Both Statement I and Statement II are correct.
  • Both Statement I and Statement II are incorrect.
  • Statement I is correct but Statement II is incorrect.
  • Statement I is incorrect but Statement II is correct.
Show Solution
collegedunia
Verified By Collegedunia

The Correct Option is A

Solution and Explanation

Statement I: Acids with an even number of carbon atoms pack more symmetrically in the crystal lattice (the terminal \(\mathrm{CH_3}\) and \(\mathrm{COOH}\) lie on opposite sides), giving stronger intermolecular forces and a higher melting point than the neighbouring odd-carbon acids. Correct.
Statement II: The lower acids are miscible with water through hydrogen bonding, but as the non-polar alkyl chain grows the hydrophobic part dominates and solubility decreases with increasing molar mass. Correct.
Both statements are correct.
Answer: (1) Both Statement I and Statement II are correct.
Was this answer helpful?
0
0