Step 1: Analyze the complex.
The given compound is \([Co(NH_3)_5Cl]Cl_2\).
- Inside the coordination sphere: \([Co(NH_3)_5Cl]^{2+}\).
- Outside the coordination sphere: 2 Cl$^-$ ions.
Step 2: Dissociation in aqueous solution.
\[
[Co(NH_3)_5Cl]Cl_2 \;\; \xrightarrow{H_2O} \;\; [Co(NH_3)_5Cl]^{2+} + 2Cl^-
\]
Step 3: Count total ions.
- 1 cation: \([Co(NH_3)_5Cl]^{2+}\)
- 2 anions: Cl$^-$ ions
Total = \(1 + 2 = 3\) ions
Step 4: Final Answer.
Thus, the total number of ions in solution is 3.
\[
\boxed{3}
\]
(i) Draw the diagram which indicates the splitting of d-orbitals in tetrahedral field.
(ii) Write any one limitation of valence bond theory.
(i)[Ni(CN)₄]²⁻ and [Ni(CO)(_4)] have different structures, but do not differ in their magnetic behaviour. Explain.
(ii) Write the formula of Tetraamineaquachloridocobalt(III)chloride.
(i) Write two postulates of Werner's coordination theory.
(ii) Draw the geometrical isomers of [(NH_3)_3(NO_2)_3] and give their structures.