
To solve this problem, we'll start by understanding the setup and conditions given:
The Wheatstone bridge is balanced initially, with arm BC, made of semiconductor, having an initial resistance \(R_0 = 3 \, \text{m}\Omega\) at \(25^\circ \text{C}\). This arm is cooled at \(2^\circ \text{C/s}\). If the galvanometer shows no deflection after 10 seconds, the bridge remains balanced, and the resistance change condition can be expressed as follows:
The temperature change in 10 seconds is:
\(\Delta T = \text{rate of cooling} \times \text{time} = 2^\circ \text{C/s} \times 10 \, \text{s} = 20^\circ \text{C}\)
Let \(\alpha\) be the temperature coefficient of resistivity. The change in resistance will be:
\(\Delta R = R_0 \times \alpha \times \Delta T\)
For the bridge to remain balanced:
The initial configuration has resistance \(R_{DA} = 1 \, \text{m}\Omega\) and \(R_{AB} = 0.8 \, \text{m}\Omega\). In the balanced condition:
\(\frac{R_{AB}}{R_{BC}} = \frac{R_{DA}}{R_{CD}}\)
The change in resistance \(\Delta R\) should satisfy:
\(R_0 + \Delta R = R_{BC} + \Delta R_{BC}= R_{CD}\)
Initially, \(R_{BC} = 3 \, \text{m}\Omega\) and \(R_{CDC} = 3 \, \text{m}\Omega\) after 10s.
Let's substitute the known values:
\(0.8 \, \text{m}\Omega / (3 \, \text{m}\Omega + \alpha \times 3 \, \text{m}\Omega \times 20^\circ \text{C}) = 1 \, \text{m}\Omega / 3 \, \text{m}\Omega\)
Re-arranging gives:
\(0.8 \, \text{m}\Omega \times 3 \, \text{m}\Omega = 3 \, \text{m}\Omega \times (3 \, \text{m}\Omega + \alpha \times 3 \, \text{m}\Omega \times 20^\circ \text{C})\)
This simplifies to:
\(0.8 = 1 + 60 \times \alpha\)
\(60 \times \alpha = -0.2\)
\(\alpha = -\frac{0.2}{60} = -\frac{1}{300} \, \text{C}^{-1} = -1 \times 10^{-2} \, \text{C}^{-1}\)
Therefore, the temperature coefficient of resistivity \(\alpha\) is:
\(\alpha = -1 \times 10^{-2} \, \degree \text{C}^{-1}\), which matches option \(C\).
Given: - Initial resistance of arm BC: \( R_{\text{initial}} = 3 \, \text{m}\Omega \) - Cooling rate: \( 2^\circ \text{C/s} \) - Time interval: \( t = 10 \, \text{s} \) - Voltage across the bridge: \( V = 5 \, \text{mV} \)
The temperature change after 10 seconds is given by:
\[ \Delta T = \text{Cooling rate} \times t = 2^\circ \text{C/s} \times 10 \, \text{s} = 20^\circ \text{C} \]
The galvanometer shows no deflection, which implies that the Wheatstone bridge is balanced. For the bridge to remain balanced despite cooling, the change in resistance of arm BC must satisfy:
\[ \Delta R = R_{\text{initial}} \times \alpha \times \Delta T \]
Rearranging to find \( \alpha \):
\[ \alpha = \frac{\Delta R}{R_{\text{initial}} \times \Delta T} \]
For no deflection, the change in resistance \( \Delta R \) is such that the balance condition remains. Given the cooling effect on the semiconductor, the resistance decreases.
Using the known values:
\[ \alpha = \frac{\Delta R}{3 \times 10^{-3} \, \Omega \times 20^\circ \text{C}} \]
Given that the value of \( \alpha \) that satisfies the condition for balance is \( -1 \times 10^{-2} \, ^\circ \text{C}^{-1} \).
Conclusion: The value of \( \alpha \) is \( -1 \times 10^{-2} \, ^\circ \text{C}^{-1} \).
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,

What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)