Step 1: Key Formula or Approach:
Since \(\vec a+\vec b+\vec c=0\), taking the dot product of both sides with itself gives \((\vec a+\vec b+\vec c)\cdot(\vec a+\vec b+\vec c) = 0\). Expanding this will bring out exactly the terms we need.
Step 2: Expanding the dot product:
\[ |\vec a|^2+|\vec b|^2+|\vec c|^2 + 2(\vec a\cdot\vec b+\vec b\cdot\vec c+\vec c\cdot\vec a) = 0 \]
Step 3: Substituting the magnitudes:
\(|\vec a|^2=9,\ |\vec b|^2=16,\ |\vec c|^2=25\), so:
\[ 9+16+25+2(\vec a\cdot\vec b+\vec b\cdot\vec c+\vec c\cdot\vec a)=0 \]
\[ 50 + 2(\vec a\cdot\vec b+\vec b\cdot\vec c+\vec c\cdot\vec a) = 0 \]
Step 4: Solving for the required sum:
\[ \vec a\cdot\vec b+\vec b\cdot\vec c+\vec c\cdot\vec a = \frac{-50}{2} = -25 \]
Final Answer:
The value is \(-25\).
\[ \boxed{-25} \]