A regular hexagon has 6 vertices. The number of ways to choose 3 vertices from 6 is given by:
\[
\binom{6}{3} = 20
\]
Step 1: Count the number of equilateral triangles
In a regular hexagon, there are exactly 2 ways to select 3 vertices that form an equilateral triangle (they must be spaced 120 degrees apart).
Step 2: Calculate the probability
The probability of selecting an equilateral triangle is:
\[
\frac{2}{20} = \frac{1}{10}
\]
Thus, the correct answer is \( \frac{1}{10} \).