To solve this problem, we need to use the relationship for adiabatic processes in ideal gases, given by the equation:
\(P_1 V_1^\gamma = P_2 V_2^\gamma\)
where:
We can rearrange this equation to find the ratio of initial pressure to final pressure:
\(\frac{P_1}{P_2} = \left(\frac{V_2}{V_1}\right)^\gamma\)
Substituting the given values \(V_1 = 5\, \text{litres}\) and \(V_2 = 4\, \text{litres}\):
\(\frac{P_1}{P_2} = \left(\frac{4}{5}\right)^{1.5}\)
Calculating \(\left(\frac{4}{5}\right)^{1.5}\):
\(\left(\frac{4}{5}\right)^{1.5} = \left(\frac{4}{5}\right) \times \sqrt{\left(\frac{4}{5}\right)} = \frac{4}{5} \times \frac{2}{\sqrt{5}} = \frac{8}{5\sqrt{5}}\)
Thus, the ratio of initial pressure to final pressure is:
\(\frac{8}{5\sqrt{5}}\)
Hence, the correct answer is \(\frac{8}{5\sqrt{5}}\).
For an adiabatic process, the relation between pressure and volume is:
\[ P_iV_i^\gamma = P_fV_f^\gamma, \] where \(\gamma = 1.5\).
Substitute the given volumes (\(V_i = 5 \, \text{litres}, V_f = 4 \, \text{litres}\)):
\[ P_i (5)^{1.5} = P_f (4)^{1.5}. \]
Rearranging for \(\frac{P_i}{P_f}\):
\[ \frac{P_i}{P_f} = \frac{(4)^{1.5}}{(5)^{1.5}}. \]
Simplify:
\[ \frac{P_i}{P_f} = \left(\frac{4}{5}\right)^{1.5}. \]
Write \(1.5\) as \(\frac{3}{2}\):
\[ \frac{P_i}{P_f} = \left(\frac{4}{5}\right)^{\frac{3}{2}} = \left(\frac{4}{5}\right)^1 \times \left(\frac{4}{5}\right)^{\frac{1}{2}}. \]
Simplify each term:
\[ \frac{P_i}{P_f} = \frac{4}{5} \times \sqrt{\frac{4}{5}} = \frac{4}{5} \times \frac{2}{\sqrt{5}} = \frac{8}{5\sqrt{5}}. \]
Final Answer: \(\frac{8}{5\sqrt{5}}\).
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,

What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)