The oxidation state of manganese in the product obtained in a reaction of potassium permanganate and hydrogen peroxide in basic medium is____.
Correct Answer: 4
Solution and Explanation
2MnO-4+3H2O2→2MnO2+3O2+2H2O+2OH-
Oxidation state of Mn in MnO2 = +4
Top Questions on reaction mechanism
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Statement II: R–CN hydrolyses under acidic medium to produce a compound which on treatment with SOCl$_2$, followed by the addition of NH$_3$ gives another compound (X). This compound (X) on treatment with NaOCl/NaOH gives a product, that on treatment with CHCl$_3$/KOH/$\Delta$ produces R–NC.
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Statement II: The mixture of p-hydroxybenzaldehyde and o-hydroxybenzaldehyde can be easily separated through steam distillation.
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(Given: Structures I and II are rigid)
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Statement II: Oxidation of \(((\text{CH}_3)_2 - \text{CH}_3\text{B})\) with hydrogen peroxide in presence of NaOH gives propan-2-ol.
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Two p-n junction diodes \(D_1\) and \(D_2\) are connected as shown in the figure. \(A\) and \(B\) are input signals and \(C\) is the output. The given circuit will function as a _______.
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A substance 'X' (1.5 g) dissolved in 150 g of a solvent 'Y' (molar mass = 300 g mol$^{-1}$) led to an elevation of the boiling point by 0.5 K. The relative lowering in the vapour pressure of the solvent 'Y' is $____________ \(\times 10^{-2}\). (nearest integer)
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- Solutions
Concepts Used:
Organic Chemistry – Some Basic Principles and Techniques - Reaction Mechanism
SN1 Reaction Mechanism:
SN1 reaction mechanism takes place by following three steps –
- Formation of carbocation
- Attack of nucleophile
- Deprotonation
SN2 Reaction Mechanism:
The SN2 reaction mechanism involves the nucleophilic substitution reaction of the leaving group (which generally consists of halide groups or other electron-withdrawing groups) with a nucleophile in a given organic compound.
Electrophilic Aromatic Substitution Reaction Mechanism:
The mechanism of an electrophilic aromatic substitution reaction contains three main components which are:
- A new sigma bond from C=C is formed during the reaction in the arene nucleophile.
- Due to the breaking of the C-H sigma bond, a proton is removed.
- The C=C bond is reformed and it restores the aromaticity of the compound.
Electrophilic Substitution Reaction Mechanism:
The electrophilic substitution reaction mechanism is composed of three steps, which will be discussed more below.
- Electrophile Generation
- Carbocation Formation
- Proton Removal