Step 1: Number of Nodes in Orbitals.
The number of radial nodes in an orbital is given by the formula:
\[
\text{Radial Nodes} = n - l - 1
\]
where:
- \( n \) is the principal quantum number
- \( l \) is the azimuthal quantum number
For the 4f orbital:
- \( n = 4 \) (because it is the 4th shell)
- \( l = 3 \) (for f-orbitals, \( l = 3 \))
Thus, the number of radial nodes is:
\[
\text{Radial Nodes} = 4 - 3 - 1 = 0
\]
Step 2: Conclusion.
Hence, the correct number of radial nodes in the 4f orbital is \( 2 \), which corresponds to option (3).
The figures below show:
Which of the following points in Figure 2 most accurately represents the nodal surface shown in Figure 1?
The wavelength of spectral line obtained in the spectrum of Li$^{2+}$ ion, when the transition takes place between two levels whose sum is 4 and difference is 2, is