Step 1: One mole of any substance contains Avogadro's number of particles, \(N_A = 6.022 \times 10^{23}\).
Step 2: Number of moles of CO given is calculated by dividing the given number of molecules by Avogadro's number.
\[\text{moles of CO} = \frac{6.02 \times 10^{24}}{6.02 \times 10^{23}} = 10 \text{ moles}\]
Step 3: The formula of carbon monoxide is CO, which means every single molecule of CO is built from exactly one carbon atom and one oxygen atom.
Step 4: Since the ratio of oxygen atoms to CO molecules is 1:1, the number of moles of oxygen (atoms) present must equal the number of moles of CO.
\[\text{moles of oxygen} = 10 \text{ moles of CO} \times 1 = 10 \text{ moles}\]
Step 5: So the number of gram-molecules of oxygen present is 10, option D.