Step 1: One Avogadro number of anything means \(6.022 \times 10^{23}\) particles of that thing. When we take \(6.022 \times 10^{23}\) atoms of an element, we have exactly 1 mole of that element, by the very definition of the mole.
Step 2: The mass of 1 mole of an element, in grams, is numerically equal to its atomic mass. This is how atomic mass units are scaled to grams using the Avogadro constant.
Step 3: Helium has an atomic mass of 4 u, its nucleus has 2 protons and 2 neutrons, giving a mass number of 4.
Step 4: So 1 mole of helium atoms, which is \(6.022 \times 10^{23}\) He atoms, has a mass of 4 grams. It is not 1 g, that would be for hydrogen atoms, not 8 g, that would be double this amount, and it should not be left as \(4 \times 6.022\times10^{23}\) g because that just restates the atom count without converting it into an actual gram value.
Answer: One Avogadro number of He atoms has a mass of 4.00 g, option B.